New method for making nanoparticles and depositing on 3D surfaces14 March 2012 A new method of making nanoparticles and nanofilms could be used to develop better electronic devices, biosensors and certain types of high-powered and highly specific microscopes used for scientific research. Engineers at the University of Arkansas and the University of Utah developed a unique chemical process to deposit gold nanoparticles onto silicon substrates. The particles are nontoxic and inexpensive to make and have superior dimensions, densities and distribution when compared to other nanoparticles and conventional methods of producing them. The unique deposition technique has the further advantage of being able to rapidly coat fragile, three-dimensional and internal surfaces at the temperature and pressure of its surroundings without requiring conductive substrates or expensive, sophisticated equipment. “Using successive thermal treatments, we characterized optical and structural features of an inexpensive, molecule-to-molecule, bottoms-up approach to create thermally stable, gold-nanoparticle ensembles on silica,” said Keith Roper, associate professor of chemical engineering at the University of Arkansas. “Images and analysis from scanning electron microscopy and atomic force microscopy revealed that particle densities are the highest reported to date. Our method also allows faster preparation than self-assembly or lithography and allows directed assembly of nanoparticle ensembles on 3D surfaces.” Deposition method The researchers’ unique approach improves upon a method that involves depositing atoms from a solution onto a substrate with a tin-sensitized surface. The researchers use a novel continuous-deposition process and then heat these deposited atoms to transform “islands” of nanoparticle material into desired forms. The resulting spherical nanoparticles can have diameters between 5 and about 300 nanometers. Roper said that microscopic images and spectroscopic data suggest that ultrathin films prepared by their new approach are smoother than conventional “sputtered” or evaporated gold films and may exhibit better optical features, such as reduced surface-roughness scattering. These features are desirable in devices such as photovoltaic cells in which narrow metal layers significantly affect local electromagnetic fields. Smoother thin films also could improve the limits of detection, sensitivity and photocurrent, respectively, in such applications. The researchers were awarded U.S. Patent No. 8,097,295 on Jan. 17 for the development.
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